Mechanism of selective p-quinol formatio
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A. Nishinaga; H. Tomita; T. Matsuura
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Article
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1980
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Elsevier Science
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French
โ 193 KB
The selective formation of e-quinols in the Co(Salpr)-catalyzed oxygenation of 4-alkyl-2,6-di-t-butylphenols in MeOH has been found to involve the rate determining reduction of peroxy-R-quinolato Co(II1) complex formed in the initial fast step. An ionic mechanism of the reduction of the O-O bond in