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Selective formation of peroxy-p-quinolato Co(III) complexes in the oxygenation of 4-alkyl-2,6-di-t-butylphenols with Co(II)-Schiff's base complexes

โœ Scribed by A. Nishinaga; H. Tomita; T. Matsuura


Book ID
108384870
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
254 KB
Volume
20
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Mechanism of selective p-quinol formatio
โœ A. Nishinaga; H. Tomita; T. Matsuura ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

The selective formation of e-quinols in the Co(Salpr)-catalyzed oxygenation of 4-alkyl-2,6-di-t-butylphenols in MeOH has been found to involve the rate determining reduction of peroxy-R-quinolato Co(II1) complex formed in the initial fast step. An ionic mechanism of the reduction of the O-O bond in

Charge distribution in Schiff-base biqui