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Selective fluorination of dichloromethane by highest oxidation state transition-metal oxide fluorides

✍ Scribed by John H. Holloway; Eric G. Hope; Paul J. Townson; Richard L. Powell


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
278 KB
Volume
76
Category
Article
ISSN
0022-1139

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The kinetics of oxidation of triethanolamine (TEA) by diperiodatoargenate(II1) anion, [Ag(HI0,)z]5-, has been studied in aqueous alkaline medium by conventional spectrophotometry. The reaction is pseudo-first-order in [Ag(III)] disappearance with kobs = (kl + &[OH-]) KlKz[TEA]/{[H210:-j+ + K1 + KIKz