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Selective dehydrochlorination of 1,1,2-tricholoroethane into 1,1-dicholoroethylene catalyzed by DBUHCl on SiO2

✍ Scribed by Isao Mochida; Hideki Watanabe; Atsuko Uchino; Hiroshi Fujitsu; Kenjiro Takeshita; Megumu Furuno; Tokio Sakura; Hitoshi Nakajima


Publisher
Elsevier Science
Year
1981
Weight
344 KB
Volume
12
Category
Article
ISSN
0304-5102

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Efficient Oxidation of 1,2-Diols into α-
✍ Toshihide Maki; Shinya Iikawa; Gen Mogami; Hitomi Harasawa; Yoshihiro Matsumura; 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB 👁 1 views

## Abstract **Get selective!** A selective oxidation of 1,2‐diols to α‐hydroxyketones catalyzed by organotin compounds has been developed (see scheme). Invaluable chemo‐ and stereoselectivity were found in the reaction. The catalytic system has been achieved by electrochemical and chemical oxidatio