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Selective dehydration of diols to allylic alcohols catalyzed by ceria

โœ Scribed by Satoshi Sato; Ryoji Takahashi; Toshiaki Sodesawa; Nozomi Honda; Hideya Shimizu

Book ID
118629852
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
88 KB
Volume
4
Category
Article
ISSN
1566-7367

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โœ Marcel Schlaf; Prasenjit Ghosh; Paul J. Fagan; Elisabeth Hauptman; R. Morris Bul ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 121 KB

The internal OH group of 1,2-propanediol is selectively removed in the deoxygenation catalyzed by [{Cp\*Ru(CO) } (ฮผ-H)] OTf (1, Cp\*=C Me , OTf=trifluoromethanesulfonate; see scheme). This reaction provides a model for deoxygenation of polyols derived from carbohydrates, for use in alternative, biom