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Selective complexation of alkali metal ions using crown ethers derived from calix[4]arenes: a computational investigation of the structural and energetic factors

โœ Scribed by Ramachandran, B. Ramu; Baker, Steven D.; Suravajhula, Girish; Derosa, Pedro A.


Book ID
111915177
Publisher
Springer Netherlands
Year
2012
Tongue
English
Weight
586 KB
Volume
75
Category
Article
ISSN
0923-0750

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Crown ether dyes with pendent anionic side-arms were synthesized for extractionspectrophotometry of alkali and alkaline earth metal ions. Dramatic changes in metal selectivity were obtained simply by changing the nature of the anionic side-arm on the same crown ether skeleton. A structure/metal sele