๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Selective cleavage of ester type glycoside-linkages and its application to structure determination of natural oligoglycosides

โœ Scribed by Kazuhiro Ohtani; Kenji Mizutani; Ryoji Kasai; Osamu Tanaka

Book ID
104233852
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
234 KB
Volume
25
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

On treatment with anhydrous LiI, 2,6-lutidine and anhydrous methanol, an ester type glycosyl linkage of acidic tri-and diterpenes was selectively cleaved without decomposition of a reducing terminal of the resulting sugar moiety to give an anomeric mixture of methyl glycosides along with an aglycone or a pro-aglycone in quantitative yield.

In this reaction, no hydrolysis of any other glycoside linkages took place.

๐Ÿ“œ SIMILAR VOLUMES

The generation of uncomplexed phenyl sel
The generation of uncomplexed phenyl selenide anion and its applicability to SN2 - type ester cleavages
โœ Dennis Liotta; William Markiewicz; Hector Santiesteban ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 166 KB

The utility of aryl selenide anions for effecting a wide variety of synthetic transformations is now well-established. 1 In this communication we wish to report a new method for generating a reactive phenyl selenide anion and the application of this anion to the facile, high-yield cleavage of alkyl