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Selective cleavage of carbon-nitrogen bonds with platinum

✍ Scribed by Guttieri, Mary J.; Maier, Wilhelm F.


Book ID
121443806
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
813 KB
Volume
49
Category
Article
ISSN
0022-3263

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Nickel peroxide selectively cleaves the s-carbon-nitrogen bond of glycine residues in dipeptide derivatives to give the corresponding amides, The glycine selectivity is attributable to preferential complexation of the reactant residue to nickel peroxide and subsequent reaction via a stable o~-centre