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Selective cis-dihydroxylation of olefins using recyclable homogeneous molybdenum acetylide catalyst

โœ Scribed by Ankush V. Biradar; Bhaskar R. Sathe; Shubhangi B. Umbarkar; Mohan K. Dongare


Book ID
103834885
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
447 KB
Volume
285
Category
Article
ISSN
1381-1169

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The use of [Mn 2 O 3 (tmtacn) 2 ](PF 6 ) 2 (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane) in combination with glyoxylic acid methylester methyl hemiacetal (GMHA) results in a highly active and hydrogen peroxide efficient catalyst for the epoxidation of olefins as well as the first homogeneous cata