✦ LIBER ✦
Selective catechol oxidations with diphenyl selenoxide. Applications to phenolic coupling.
✍ Scribed by J.P. Marino; Alan Schwartz
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 213 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Diphenyl selenoxide was used as a mild and selective oxidant in the synthesis of aporphines and homoaporphines.
An intramolecular coupling between a phenol and a catechol is believed to proceed via catechol selenurane intermediates.