Selective catalytic hydrogenation of an olefin moiety in the presence of a terminal alkyne function
✍ Scribed by Christopher J. Palmer; John E. Casida
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 188 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
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## Abstract Pd/C is used as an efficient catalyst for the copper‐free __Sonogashira__ coupling of acid chlorides and terminal alkynes to afford ynones in high yields (__Tables 1__ and __3__). Cyclization of (2‐methoxyaryl)‐substituted ynones induced by I~2~/ammonium cerium(IV) nitrate (CAN) at room