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Selective catalysis of Diels-Alder reactions of 2-methoxy-5-methyl-1,4-benzoquinone

✍ Scribed by Tou, Jacob S.; Reusch, William

Book ID
120640334
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
355 KB
Volume
45
Category
Article
ISSN
0022-3263

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The frontier molecular orbital of 5-phenylcyclopentadiene was predicted on the basis of the orbital mixing rule to deform to favor the Diels-Alder reaction in a syn contrasteric manner. The prediction was substantiated experimentally by the reactions of 5-methyl-5phenylcyclopentadiene with dienophil