A partially quaternized poly(4-vinylpyridine) mercury ยฎlm electrode (QPVP/MFE) was developed for the determination of traces of Pb(II) in real samples by square-wave anodic stripping voltammetry. In this method, Pb(II) is converted into an anionic chloride complex and preconcentrated into the QPVPyM
Selective binding of mercury ions by poly(4-vinylpyridine) hydrochloride resin
โ Scribed by B. L. Rivas; H. A. Maturana; M. Luna
- Book ID
- 101251548
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 137 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
The binding ability of poly(4-vinylpyridine) hydrochloride resin for Cu(II), Cd(II), Zn(II), Hg(II), Pb(II), Cr(III), and U(VI) was investigated. All these ions, except Hg(II), could be not removed from aqueous solutions under the same conditions. The selective sorption of Hg(II) from mixtures of ions was observed. The elution of Hg(II) bound to the resin was also investigated using various concentrations of nitric acid and perchloric acid. Due to rapid complexation, a high mercury ion-binding capacity, high selectivity, and ease of regenerability, the resin can be useful for the removal and recovery of mercury ions from aqueous solutions.
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