𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Selective and efficient synthesis of di-, tri- and tetrasubstituted 1, 10-phenanthrolines

✍ Scribed by Christiane Dietrich-Buchecker; M.Consuelo Jime´nez; Jean-Pierre Sauvage

Book ID
104261285
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
135 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

A general synthetic procedure for the preparation of multisubstituted phenanthrolines is presented. Bromination of 1,10-phenanthroline at the 3 and 8 positions, followed by Suzuki coupling reaction and subsequent methylation afford the di-, tri and tetra-substituted phenanthrolines in good yields. These phenanthroline derivatives are useful building blocks in the construction of highly sophisticated molecular architectures.

📜 SIMILAR VOLUMES

Synthesis and Properties of Tetrasubstit
Synthesis and Properties of Tetrasubstituted 1,10-Phenanthrolines and Their Ruthenium Complexes
✍ Bernhard Schäfer; Helmar Görls; Susann Meyer; William Henry; Johannes G. Vos; Sv 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB 👁 1 views

## Abstract The synthesis and the photophysical properties of a series of tetrasubstituted phenanthroline (phen) ruthenium complexes of the type [Ru(tbbpy)~2~(phen‐R~4~)]^2+^ (tbbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridine; phen = 1,10‐phenanthroline; R represents the substitution at 3‐, 5‐, 6‐ and