Selective Amination of Cyanuric Chloride in the Presence of 18-Crown-6
β Scribed by Simona Samaritani; Paola Peluso; Corrado Malanga; Rita Menicagli
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 237 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-193X
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π SIMILAR VOLUMES
## Abstract Reaction of TiF~4~ and 18βcrownβ6 in MeCN affords the molecular complex [(__cisβ__TiF~4~)~2~(18βcrownβ6)] (1) only. Water and THF displace the 18βcrownβ6 in the tetrafluoro complex 1, with the formation of __cisβ__TiF~4~L~2~. The complex __cisβ__TiF~4~(H~2~O)~2~ and 18βcrownβ6 form [{__
The addition of lithium chloride promoted the coupling reaction of hydrocarbon solutions of poly(styryl)lithium (PSLi) and poly(isoprenyl)lithium (PILi) with 3-dimethylaminopropyl chloride to form the corresponding -dimethylamino-functionalized polymers. Quantitative amine functionalization was achi