Segmented Block Copolymers with Monodisperse Hard Segments: The Influence of H-Bonding on Various Properties

✍ Scribed by Gerard J. E. Biemond; Jan Feijen; Reinoud J. Gaymans

• Publisher: John Wiley and Sons
• Year: 2009
• Tongue: English
• Weight: 492 KB
• Volume: 294
• Category: Article
• ISSN: 1438-7492
• DOI: 10.1002/mame.200900093

✦ Synopsis

Abstract

The properties of segmented‐copolymer‐based H‐bonding and non‐H‐bonding crystallisable segments and poly(tetramethylene oxide) segments were studied. The crystallisable segments were monodisperse in length and the non‐hydrogen‐bonding segments were made of tetraamidepiperazineterephthalamide (TPTPT). The polymers were characterised by DSC, FT‐IR, SAXS and DMTA. The mechanical properties were studied by tensile, compression set and tensile set measurements. The TPTPT segmented copolymers displayed low glass transition temperatures (T~g~, −70 °C), good low‐temperature properties, moderate moduli (G′ ≈ 10–33 MPa) and high melting temperatures (185–220 °C). However, as compared to H‐bonded segments, both the modulus and the yield stress were relatively low.

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