## Abstract The first detailed application of a recently published very general approach to chemical equilibria during sedimentation is presented. As a consequence of the very extensive theoretical treatment, made possible by this approach, the active enzyme analytical centrifugation method can now
Sedimentation of generalized systems of interacting particles. III. Concentration-dependent sedimentation and extension to other transport methods
✍ Scribed by Jean-Michel Claverie
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1976
- Tongue
- English
- Weight
- 790 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0006-3525
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✦ Synopsis
Abstract
The simulation method presented in the previous papers is related to the concentration‐dependent sedimentation–diffusion. It can be shown that the efficiency of the program described previously is maintained. A simulation of a system exhibiting the Johnston–Ogston effect is presented.
Through the similarity of their continuity equations with the Lamm equation, electrophoresis, molecular sieve, and chromatography are treated. A general simulation of transport for systems of many interacting components is thus presented, which is able to take into account kinetically controlled chemical reactions and nonideal phenomena.
📜 SIMILAR VOLUMES
## Abstract The transport coefficients of macromolecular solutes are normally extrapolated to “infinite dilution” to remove the effects of concentration‐dependence terms, for which no satisfactory general treatment has been available. It is shown that a simple general treatment for the concentratio