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Secoorthosiphols A–C: three highly oxygenated secoisopimarane-type diterpenes from Orthosiphon stamineus
✍ Scribed by Suresh Awale; Yasuhiro Tezuka; Seikichi Shimoji; Kazuhiko Taira; Shigetoshi Kadota
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 68 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Three new highly oxygenated 2,3-secoisopimarane-type diterpenes, named secoorthosiphols A (1), B (2) and C (3), have been isolated as extremely minor constituents from the aerial parts of the Orthosiphon stamineus from Okinawa. A unique unprecedented structural feature of such a ring A opened system in newly isolated compounds was encountered for the first time in isopimarane-type diterpenes. Secoorthosiphol C (3) represents the first example of a biogenetically unique and unconventional secoisopimarane-type diterpene having a cyano group.
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