Secondary structure of peptides: 15. 13C n.m.r. CP/MAS study of solid elastin and proline-containing copolyesters
✍ Scribed by Hans R. Kricheldorf; Detlef Müller
- Book ID
- 119069978
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 734 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0141-8130
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Rheinstetten 4, Federal Republic of Germany ## Synopsis Various copolypeptides were prepared by benzylamine or tertiary amine-initiated copolymerizations of alanine-N-carboxyanhydride (Ah-NCA) and valine-N-carboxyanhydride (Val-NCA). The number-average molecular weights of these copolypeptides we
## Abstract Primary and tertiary amine‐initiated polymerizations of L‐alanine‐__N__‐carboxyanhydride (L‐Ala‐NCA) were conducted at 20 or 100°C in a variety of solvents. The 75.5‐MHz ^13^C‐nmr CP/MAS spectra of the resulting poly(L‐alanines) revealed that all samples contain both α‐helix and pleated