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Secondary ROS or peroxides after singlet oxygen production

โœ Scribed by I. Lhommeau; S. Douillard; E. Bigot; P. Guerin; M. Krempf; R. Bataille; T. Patrice


Book ID
116823264
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
82 KB
Volume
8
Category
Article
ISSN
1572-1000

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Concerning zwitterionic peroxide or dira
โœ Sr.M.Bellarmine Grdina; M. Grdina; M. Orfanopoulos; L.M. Stephenson ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Arguments are presented which show that zwitterionic or diradical intermediates in the singlet oxygen-olefin ene reaction would lead to a prediction that geminal groups would be competitive in the C-H abstraction reaction. Isotope effect data available from previous studies clearly show that such is