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Secondary Kinetic Deuterium Isotope Effects in the Reaction of MeI with Organoplatinum(II) Complexes

✍ Scribed by Rashidi, Mehdi; Nabavizadeh, S. Masoud; Akbari, Alireza; Habibzadeh, Sepideh

Book ID
125855685
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
117 KB
Volume
24
Category
Article
ISSN
0276-7333

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Chorismate synthase (EC 4.6.1.4) is the shikimate pathway enzyme that catalyzes the conversion of 5-enolpyruvylshikimate 3-phosphate (EPSP) to chorismate. The enzyme reaction is unusual because it involves a trans-1,4 elimination of the C-3 phosphate and the C-6 proR hydrogen and it has an absolute