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Secondary Deuterium Kinetic Isotope Effects on the Isomerization of the Trimethylene Diradical to Cyclopropane

โœ Scribed by Baldwin, John E.; Freedman, Teresa B.; Yamaguchi, Yukio; Schaefer, Henry F.


Book ID
120525634
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
69 KB
Volume
118
Category
Article
ISSN
0002-7863

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The addition of HOBr to allene secondary
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Electrophilic additions to allene interestingly proceed with orientations for addition which are very much dependent upon the nature of the electrophile. 2 Additions involving a proton as the reactive electrophile, for example, proceed with almost exclusive attack at the