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Second-sphere coordination of transition-metal complexes by calix[4]arenes

โœ Scribed by Atwood, Jerry L.; Orr, G. William; Hamada, Fumio; Vincent, Rebecca L.; Bott, Simon G.; Robinson, Kerry D.

Book ID
120426644
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
297 KB
Volume
113
Category
Article
ISSN
0002-7863

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Addition of p-tert-butylcalix[4]arene LH 4 to the dinuclear ported by two bridging ยต 2 -ฮบ 2 O,ฮบ 2 O-calix[4]arene ligands in compounds M 2 (NMe 2 ) 6 (M = Mo, W) results in the formation the solid state. These compounds are the first examples of a of [NH 2 Me 2 ] 2 [L 2 M 2 ] 1 (M = Mo) and 2 (M = W