✦ LIBER ✦

Search for the kramers theory turnover: photochemical isomerization at very low viscosities

✍ Scribed by Scott H. Courtney; Graham R. Fleming

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 356 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85273-2

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✦ Synopsis

The rate of photochemical isomerization of diphenyl butadiene has been studied as a function of viscosity and temperature in liquid ethane and propane. The lowest viscosity studied is about one order of mamitude lower than our previous study. No evidence for a turnover or deaease in rate with decreasing viscosity was found.