Search for phonon anomalies in the intermediate valence compound CeSn3
✍ Scribed by L. Pintschovius; E. Hollan-Moritz; D. Wohlleben; S. Stähr; J. Liebertz
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 831 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0038-1098
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Two new phases, Yb 1؊x Al 3؊x Si x and Yb 1؊y Al 3؊x Ge x , were found by systematic investigations of the according ternary systems. The crystal structures of Yb 1؊y Al 2.8 Si 0.2 and Yb 1؊y Al 2.8 Ge 0.2 (defect HT-PuAl 3 type) were studied by X-ray powder methods (CuK 1 radiation, ؍ 1.54056 A >
## Abstract The title complex crystallises in two __C__~__3v__~, isomeric forms differing in carbonyl‐ligand arrangement. In solution, the isomer 1b with three edge‐bridging carbonyls on a common face of the metal tetrahedron converts __via__ an endothermic equilibrium into the isomer 1u with no br