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Scope, limitations, and mechanism of the homoconjugate electrophilic addition of hydrogen halides

โœ Scribed by Lambert, Joseph B.; Napoli, James J.; Johnson, Katharine Kappauf; Taba, Kalulu N.

Book ID
120183363
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
709 KB
Volume
50
Category
Article
ISSN
0022-3263

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The mechanism of 1,2-addition reactions of HF and HCl to Si=Si, Si=C, and C=C bonds has been investigated by ab initio quantum chemical methods. Geometries and relative energies of the stationary points and all the transition states were determined by using the MP2/6-311++G(d,p), B3LYP/6-311++G(d,p)