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Scope and mechanism of the reaction of alkylidenephosphoranes with nitriles

✍ Scribed by Barnhardt, Robert G.; McEwen, William E.


Book ID
120458695
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
740 KB
Volume
89
Category
Article
ISSN
0002-7863

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Kinetic studies of the reaction of diphenylphosphinodithioic acid with nitriles support a two step mechanism, the first step being an "ene" reaction. In the preceeding communication we described the use of diphenylphosphinodithioic acid (1) as a reagent for the rapid conversion of nitriles to thioa