𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Scission of oxiranes by acid anhydrides to unsaturated alcohol esters

✍ Scribed by A. A. Gevorkyan; P. I. Kazaryan; S. V. Avakyan; É. S. Simonyan

Book ID
104781375
Publisher
Springer US
Year
1989
Tongue
English
Weight
320 KB
Volume
25
Category
Article
ISSN
0009-3122

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A simple catalytic system for the substi
A simple catalytic system for the substitutive carbonylation of allyl alcohols to β,γ-unsaturated acids or esters
✍ Bartolo Gabriele; Giuseppe Salerno; Mirco Costa; Gian Paolo Chiusoli 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 529 KB

Ally1 alcohols can be efficiently carbonylated to /3,y-unsaturated acids or esters in dimethylacetamide (DMA) or MeOH/DMA mixtures under relatively mild conditions (8O"C, 50-100 atm) using a simple catalytic system consisting of palladium iodide in the presence of thiourea as ligand. In the case of