✦ LIBER ✦

Schemes for the shifting of shield supports

✍ Scribed by A. A. Dobriyan; V. N. Kulakov; L. V. Zimonin

Book ID: 110557228
Publisher: Springer
Year: 1999
Tongue: English
Weight: 428 KB
Volume: 35
Category: Article
ISSN: 1573-8736
DOI: 10.1007/bf02562448

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It is generally accepted l-9 that chemical shifts induced by lanthanide shift reagents are predominantly or entirely due to a dipolar shielding mechanism. Assuming axial symmetry lo the dipolar shifts Ai are given by the McConnell-Robertson equation (1)11 where C is a proportion-Ai = C(I -3cos2ei)/R