The present article considers the coil-to-globule transition behavior of atactic and syndiotactic poly(methyl methacrylates), (PMMA) in their theta solvent, n-butyl chloride (nBuCl). Changes in Rh in these polymers with temperature in dilute theta solutions were investigated by dynamic light scatter
Scattering Function of Syndiotactic Poly(methyl methacrylate) in Dilute Solution
β Scribed by Yoshizaki, Takenao; Hayashi, Hisao; Yamakawa, Hiromi
- Book ID
- 125982198
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 519 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
## Abstract Association of syndiotactic (s) poly(methyl methacrylates) (PMMAs) in toluene, benzene, and acetonitrile has been studied by NMR spectroscopy, osmometry, and viscometry. It was found that in solutions of highly syndiotactic PMMA in toluene, most of the polymer exists in the associated s
## SYNOPSIS Randomly branched poly(methy1 methacrylate) samples were prepared by copolymerization with different amounts of ethylene dimethacrylate. The molecular weight distributions, radius of gyration distributions, and intrinsic viscosity distributions were measured by size exclusion chromatog