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Scanning Tunneling Microscopy and Spectroscopy of Non-Doped, Hydrogen Terminated CVD Diamond

✍ Scribed by Cannaerts, M. ;Nesl�dek, M. ;Remes, Z. ;Van Haesendonck, C. ;Stals, L.M.


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
95 KB
Volume
181
Category
Article
ISSN
0031-8965

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✦ Synopsis


The electron emission from a diamond surface is influenced by the surface termination and the surface density of states. It is known that the hydrogen termination of diamond surfaces induces ptype conduction. Scanning tunneling spectroscopy (STS), combined with high-resolution topographical imaging with the scanning tunneling microscope (STM), enables to investigate local variations in the electronic structure of surfaces. We show that the hydrogen termination is sufficient to obtain reproducible STM and STS measurements. We find that the formation of a Schottky point contact between tip and sample gives rise to a rectifying I ±V characteristic. Retracting the tip results in a change in the I ±V characteristics from a rectifying behavior towards normal tunneling behavior. The tunneling measurements confirm the surface p-type conductivity and Fermi level pinning at the valence band.