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Scanning probe microscopic imaging of guanine on a highly oriented pyrolytic graphite electrode

✍ Scribed by A.-M Chiorcea; A.M Oliveira-Brett


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
252 KB
Volume
55
Category
Article
ISSN
1567-5394

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✦ Synopsis


Guanine adsorbed onto a highly oriented pyrolytic graphite electrode was studied by MAC-Mode Atomic Force Microscopy (AFM), and the electrochemical behaviour of the guanine layer was investigated with Electrochemical AFM. Guanine adsorbs spontaneously, without forming a well-packed structure, into nucleation spots, which are stable with time and cover the surface uniformly and almost completely. The process of guanine adsorption and nucleation can be controlled and the effect of altering the exposure time and varying the potential was investigated.


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Pre-existing defects in the surface of highly-oriented pyrolytic graphite (HOPG) can be etched out by reaction with oxygen at high temperature. The result of this treatment is a population of one-monolayer-deep etch pits on the surface. An etch pit edge, possessing different chemical terminations th