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Scandium triflate-catalyzed 1,3-dipolar cycloaddition of aziridines with alkenes

✍ Scribed by J.S Yadav; B.V.Subba Reddy; Sushil Kumar Pandey; P Srihari; I Prathap

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 241 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02008-1

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✦ Synopsis

Phenyl aziridines undergo 1,3-dipolar cycloaddition efficiently with olefins such as cyclic enol ethers and allyltrimethylsilane in the presence of a catalytic amount of Sc(OTf) 3 at ambient temperature to afford the corresponding pyrrolidine derivatives in high yields with high regioselectivity.

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