Scale-up studies of the electrolytic reduction of oxalic to glyoxylic acid
β Scribed by F. Goodridge; K. Lister; R. E. Plimley; K. Scott
- Publisher
- Springer
- Year
- 1980
- Tongue
- English
- Weight
- 600 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0021-891X
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π SIMILAR VOLUMES
We carried out a theoretical treatment of the reduction of o-keto acids, the limiting current of which typically reaches a maximum value at a given pH. Provided the protonated form of an a-keto acid is strongly hydrated in solution and the protonation equilibria involved are substantially faster th
Optically-inactive ketones, which have a chirality center at their a-positions, were electrolytically reduced to the corresponding diastereomeric secondary alcohols. The isomeric ratio of the alcohols depended on the substituent of the ketones and on electrolytic conditions. It is noticeable that a