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Sb-induced size effects in ZnO nanocrystallites

✍ Scribed by Jian Zuo; Cunyi Xu; Lihua Zhang; Baokun Xu; Ruo Wu


Book ID
102431535
Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
125 KB
Volume
32
Category
Article
ISSN
0377-0486

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✦ Synopsis


Abstract

Sb‐doped ZnO nanocrystallites of average grain size about 10 nm were made by using the citrate method. Raman spectra of the Sb‐doped ZnO nanocrystallites at room temperature are reported. Shifts and broadening of the Raman peak with Sb increasing content were observed and it was found that the intensity of a new Raman peak increased at the same time. These effects are similar to finite size effects in ZnO nanocrystallites. It was found for the first time that the size effects are induced by the presence of Sb in the matrix. Copyright Β© 2001 John Wiley & Sons, Ltd.


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## Abstract We report a first‐principles study on several series of zinc oxide prismatic nanoparticles (NPs) with triangular and hexagonal cross‐section geometries and various diameters up to 2.4 nm. Structural and electronic properties of the NPs are calculated using density functional theory, foc