𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Saturation Spectrum of the ν2/ν4Dyad of AsH3

✍ Scribed by G. Spiegl; W.A. Kreiner

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
710 KB
Volume
187
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

The n 2 / n 4 dyad of arsine, AsH 3 , has been investigated between 875 and 1100 cm 01 by laser sideband spectroscopy. In total 189 transitions have been observed with sub-Doppler resolution ( É300 kHz ) and measured to an absolute accuracy of about 100 kHz. These data may be useful to serve as a secondary frequency standard. Our observations include four perturbation-allowed transitions with D( k 0 l ) Å 3. Saturation spectra of dipole forbidden transitions had not been previously reported for arsine. Quadrupole hyperfine structure, as well as vibrationrotation splitting of Ék 0 lÉ Å 3N levels in both fundamentals, has been analyzed. Combining our results with MW and RF data ( 239 frequencies ) reported in the literature, a total of 882 transition frequencies were available to fit 15 ground state parameters and 48 excited state parameters of the n 2 / n 4 dyad. The standard deviation of the fit is 245 kHz.

📜 SIMILAR VOLUMES

High-Resolution Infrared Spectrum of ν5,
High-Resolution Infrared Spectrum of ν5, ν4, ν3, ν4+ ν5, and 2ν4Band Systems of Deuterobromoacetylene
✍ Robert Brotherus; Olavi Vaittinen; Lauri Halonen; Hans Bürger; Oliver Polanz 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 480 KB

High-resolution vibration-rotation spectra of gas-phase deuterobromoacetylene have been recorded in the 240-990 cm-1 infrared region. The analyzed band systems are rich in hot bands and have a high density of lines. Five band systems and a total of 124 vibration-rotation bands of the isotopic specie

The High-Resolution Infrared Spectrum of
The High-Resolution Infrared Spectrum of the ν1/2ν2Fermi Dyad Bands of COF2
✍ Romola D'Cunha; V.A. Job; G. Rajappan; V.Malathy Devi; W.J. Lafferty; A. Weber 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 337 KB

High-resolution FTIR data of carbonyl fluoride in the region of the C-O stretch n 1 fundamental have been analyzed. Satisfactory interpretation of the spectral data required a rigorous analysis that involved the inclusion of Fermi resonance with the 2n 2 state and Coriolis interaction with the 2n 3

Infrared Spectrum of Ozone in the 4600 a
Infrared Spectrum of Ozone in the 4600 and 5300 cm−1Regions: High Order Accidental Resonances through the Analysis of ν1+ 2ν2+ 3ν3− ν2, ν1+ 2ν2+ 3ν3, and 4ν1+ ν3Bands
✍ A. Barbe; J.J. Plateaux; S. Mikhailenko; Vl.G. Tyuterev 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 334 KB

The very weak bands nu1 + 2nu2 + 3nu3 and 4nu1 + nu3 of 16O3 have been observed for the first time, using the Fourier transform spectrometer (FTS) of Reims and the usual experimental setup providing a large product p x l of approximately 38 Torr x 36 m. The upper levels of these A-type bands which a

The FT-IR Spectrum of HC15NO: The ν1, ν2
The FT-IR Spectrum of HC15NO: The ν1, ν2, 2ν3, and ν2 + ν3 Band Systems
✍ W. Quapp; S. Albert; B.P. Winnewisser; M. Winnewisser 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 736 KB

The infrared spectrum of \(\mathrm{HC}^{15} \mathrm{NO}\), an isotopically substituted species of fulminic acid, has been measured in the range \(1900-3600 \mathrm{~cm}^{-1}\) at a resolution of \(0.003 \mathrm{~cm}^{-1}\) with a Bruker IFS \(120 \mathrm{HR}\) interferometer. More than 100 subbands