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Saturated analogs of poison ivy allergens. Synthesis of trans,trans- and cis,trans-3-alkyl-1,2-cyclohexanediols and sensitizing properties in allergic contact dermatitis

✍ Scribed by Lepoittevin, Jean Pierre; Benezra, Claude

Book ID: 126973751
Publisher: American Chemical Society
Year: 1986
Tongue: English
Weight: 658 KB
Volume: 29
Category: Article
ISSN: 0022-2623
DOI: 10.1021/jm00152a018

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Cyclohexane analogs of poison ivy and poison oak derivatives. A totally stereoselective synthesis of trans,trans-3-alkyl-1,2-cyclohexanediols.

✍ Jean-Pierre Lepoittevin; Claude Benezra 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 110 KB

Pure trans,trans-3-methyl-, 3-n-pentyl,3-n-decyl-and 3n-pentadecyl-1.2-cyclohexanediols have been prepared in two steps, in 55-70% overall yields from 2-cyclohexenone.