The extra peak. located at LX 13.6 eV on the high-bilidin~~ner~y side of the cure levels cf titenium in rutile, : anafase and barium titanate, probably arises from a shake-up process involving an O(2p) -, Ti(4s) transition. :
Satellite Phenomena in X-ray photoelectron spectra of actinide compounds
โ Scribed by G.C. Allen; P.M. Tucker
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 380 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Satellite structure to one side of the 4f photoelectron lines of a number of thorium compounds has been investigated. The origin of these and similar lines observed in uranium compounds is discussed together with those recorded near the 3d phoioekron signals of lanthanide compounds.
๐ SIMILAR VOLUMES
## XF'S spectra of a number of paramagnetic Co compounds are studied and the correlation bctween the intensity of thc Co 2~3,~ satellite and the mapitude of its magnetic moment is shown. A new approach is put forward to e?rpIti the experimental data.
The correlation between paramagnetism and the shnkc-up wlcllites in the X-ray photoelcclron spectra of the 3d transition-metal compounds is examined and explained in wrms OP modified sehxtion rules governing ~hc shake-up Volume 14. number I CIIEhllCAL PHYSICS LETTERS
Exatiination of the various &r&ions liable to contribute to stetite profiles in X-ray photoelectron spectra of 3d-transition metal compounds is intended Lo show the inadequacy of the monopble selection rule which has been wed to account for the app.zrent conelztion between satellite!; and pammagneti