Sample evaporation in conventional split/splitless GC injectors. Part 3: Retaining the liquid in the vaporizing chamber

✍ Scribed by Grob, Konrad ;De Martin, Mirelia

• Book ID: 102894113
• Publisher: John Wiley and Sons
• Year: 1992
• Tongue: English
• Weight: 669 KB
• Volume: 15
• Category: Article
• ISSN: 0935-6304
• DOI: 10.1002/jhrc.1240150609

✦ Synopsis

Abstract

As most sample liquids tend to pass through an empty injector insert at a speed which is too high to enable complete evaporation, movement of the liquid must be arrested before it reaches the column entrance. Stopping the liquid means deposition on to a surface; this, however, is possible only after the temperature of the surface has been cooled to (or below) the boiling point of the liquid (solvent).

The performance of different means of stopping the liquid has been tested visually (by the method described in Part 2). Baffles on the wall of the injector insert had hardly any effect on evaporation: the band of liquid leaving the syringe needle performed a perfect slalorn around them. The inverted cup proved more efficient, but the best performance was obtained from a light plug of glass wool: owing to its low thermal mass, the first fibers to be met by the liquid are immediately cooled to the solvent boiling point, allowing the liquid to wet it. The sample liquid is sucked up by the glass wool, from where the sample evaporates relatively slowly, often over a period of several seconds.