Sm(CO~3~)(OH) was obtained hydrothermally from an aqueous solution of samarium oxide, formic acid, triethylenetetramine and dimethylformamide. The structure features decacoordinated samarium (site symmetry __m__) with carbonate and hydroxide acting as bridging ligands.
โฆ LIBER โฆ
Samarium(III) formate
โ Scribed by Xu, Yan ;Ding, Shao-Hua ;Zhou, Guang-Peng ;Liu, Yu-Guo
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 242 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
โฆ Synopsis
The title compound, poly[samarium(III)-tri--formato], [Sm(HCO 2 ) 3 ] n , is isostructural with numerous lanthanide formates and comprises a three-dimensional framework assembled from SmO 9 polyhedra and HCO 2 ร anions. The Sm atom lies on a site of 3m symmetry and is coordinated by nine O atoms in a typical coordination geometry. The formate anions lie on mirror planes.
๐ SIMILAR VOLUMES
Samarium(III) carbonate hydroxide
โ
Xu, Yan ;Ding, Shao-Hua ;Feng, Wun-Jun ;Zhou, Guang-Peng ;Liu, Yu-Guo
๐
Article
๐
2006
๐
International Union of Crystallography
๐
English
โ 232 KB
Octaยญureaยญsamarium(III) triiodide
โ
Savinkina, Elena V. ;Ansari, Yana F. Al ;Zamilatskov, Ilia A. ;Albov, Dmitry V.
๐
Article
๐
2005
๐
International Union of Crystallography
๐
English
โ 154 KB
Synthesis and properties of neptunium(II
โ
K. Schwochau; J. Droลผdลผyลski
๐
Article
๐
1980
๐
Elsevier Science
โ 137 KB
The thermal decomposition of iron(III) f
โ
Pedro J. Morando; Norma H. Piacquadรญo; Miguel A. Blesa; Carlos O. Della Vedova
๐
Article
๐
1987
๐
Elsevier Science
๐
English
โ 395 KB
Lanthanum(III), cerium(III), praesodymiu
โ
B. L. Kalsotra; S. K. Gupta; R. N. Kapoor
๐
Article
๐
1977
๐
Springer
๐
English
โ 129 KB
The enthalpy of formation of samarium tr
โ
Y.-C. Kim; J. Oishi; S.-H. Kang
๐
Article
๐
1977
๐
Elsevier Science
๐
English
โ 342 KB