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Samarium Diiodide Mediated Coupling of Aroyl Chlorides

✍ Scribed by Zhi-Farig U; Yong-Min Zhang

Book ID
102101419
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
203 KB
Volume
19
Category
Article
ISSN
0256-7660

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Acid chlorides react with esters in the presence of samarium diiodide and catalytic amounts of NiI 2 to afford samarium enediolates which can further react with electrophiles such as water or aldehydes to give respectively ct-ketols or ct-dihydroxyketones.