𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Samarium diiodide initiated addition reaction of fluoroalkyl iodides to olefins

✍ Scribed by Xiyan Lu; Shengming Ma; Jingyang Zhu

Book ID
108381756
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
131 KB
Volume
29
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Studies on samarium diiodide initiated a
Studies on samarium diiodide initiated addition reaction of fluoroalkyl iodides to alkynes and its mechanism
✍ Shengming Ma; Xiyan Lu πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 423 KB

Abetract: Samarium diiodide was found to be an effective initiator in the addition reaction of fluoroalkyl iodides to alkynes. A single electrontransfer radical chain mechanism was proposed for the reaction based on ESR studies and other experimental results. Samarium diiodide, a strong single-elec

Electron Transfer Initiated Free Radical
Electron Transfer Initiated Free Radical Additions of Perfluoroalkyl Iodides and Diiodides to Alkenes
✍ Metzger, JΓΌRgen O. ;Mahler, Ralf ;Schmidt, Andreas πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 393 KB

## Abstract Perfluoroalkyl iodides were added in very good yields to 1,2‐dialkyl substituted double bonds of e.g. petroselinic acid initiated by lead/copper(II) acetate in methanol and by copper without solvent, respectively. Using the new initiator system lead/copper(II) acetate, we also obtained