Salt-induced conversions of P(V) into P(
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Marianne M. C. F. Castelijns; Dirk van Aken; Pieter Schipper; Johan J. C. van Li
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Article
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2010
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Elsevier Science
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English
⚖ 444 KB
## Abstract Evidence is presented for the involvement of pentaco‐ordinated phosphorus intermediates in the rate‐determining step of the de‐alkylation reactions of some phosphates and phosphonates with LiCl and LiBr. Such involvement is suggested to lead to the zwitterionic pentaco‐ordinated phospho