✦ LIBER ✦

Salt Effects on the Formation of the Rotaxane [Ru(NH3)5(4,4′-bpy)/β-CD/Fe(CN)5]−

✍ Scribed by M. Lopez-Lopez; P. Lopez-Cornejo

Book ID: 106430543
Publisher: Springer US
Year: 2011
Tongue: English
Weight: 474 KB
Volume: 40
Category: Article
ISSN: 0095-9782
DOI: 10.1007/s10953-011-9746-7

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Resonance-enhanced Raman scattering in t

Resonance-enhanced Raman scattering in the near-infrared region. Preliminary studies of charge transfer in the symmetric dimers (2,2'-bpy)2ClRu-4,4'-bpy-RuCl(2,2'-bpy)24+/3+/2+, (H3N)5Ru-4,4'-bpy-Ru(NH3)56+/5+/4+, and (NC)5Fe-4,4'-bpy-Fe(CN)54-/5-/6-

✍ Doorn, S. K.; Hupp, Joseph T.; Porterfield, D. R.; Campion, A.; Chase, D. B. 📂 Article 📅 1990 🏛 American Chemical Society 🌐 English ⚖ 434 KB

Salt and Solvent Effects on the Kinetics

Salt and Solvent Effects on the Kinetics and Thermodynamics of the Inclusion of the Ruthenium Complex [Ru(NH 3 ) 5 (4,4‘-bpy)] 2+ in β-Cyclodextrin

✍ Martin, C.; Sanchez, F.; Jimenez, R.; Prado, R.; Perez-Tejeda, P.; Lopez-Cornejo 📂 Article 📅 2006 🏛 American Chemical Society 🌐 English ⚖ 57 KB

Micellar effects on a ligand substitutio

Micellar effects on a ligand substitution reaction: Kinetics of the formation of [Fe(CN)5(μ-pz)Ru(NH3)5]−, from [Fe(CN)5H2O]3− and [Ru(NH3)5pz]2+, in the presence of anionic micelles

✍ Rafael Jiménez; Elena Bueno; Israel Cano; Elizabeth Corbacho; M. Eugenia Fernánd 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB 👁 2 views

## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i

Asymmetric salt effects on anion/cation

Asymmetric salt effects on anion/cation reactions: A comparative study of the [Fe(CN)6]4− + [Co(NH3)5pz]3+ and [Ru(NH3)5pz]2+ + [Co(C2O4)3]3− reactions

✍ F. Muriel; R. de la Vega; F. Sánchez; R. Jiménez; R. Prado-Gotor; F. Pérez; P. P 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 2 views

## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__

Solvent and salt effects on the kinetics

Solvent and salt effects on the kinetics of the reaction between [Ru(NH3)5pz]2+ and [Fe(CN)5H2O]3–

✍ R. Prado-Gotor; A. Ayala; A. B. Tejeda; M. B. Suárez; C. Mariscal; M. D. Sánchez 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 112 KB 👁 2 views

## Abstract The kinetics of replacement of H~2~O by [Ru(NH~3~)pz]^2+^ (pz = pyrazine) in [Fe(CN)~5~H~2~O]^3−^ have been studied in various concentrated electrolyte solutions and in various water–cosolvent mixtures, at 298 K. Salt and cosolvent effects can be rationalized taking into account specifi

Salt effects upon reactions of different

Salt effects upon reactions of different charge type reactants: Peroxodisulphate Oxidations of Fe(CN)4(bpy)2−, cis-Fe(CN)2(bpy)2 and Fe(bpy)32+ and Iron(II) Oxidation by Co(NH3)5Cl2+

✍ Ernestina Múñoz; María Del Mar Graciani; Rafael Jiménez; Amalia Rodríguez; María 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 490 KB 👁 1 views

## Abstract Salt effects on the oxidation of the iron(II) complexes Fe(CN)~4~(bpy)^2−^, __cis__‐(CN)~2~(bpy)~2~ and Fe(bpy)~3~^2+^ by S~2~O~8~^2−^ as well as on the reaction Fe^2+^ + Co(NH~3~)~5~Cl^2+^ have been studied in concentrated electrolyte solutions at 298.2 K. We have gone from anion–anion