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Salt Effects on the Conformational Behavior of 5-Carboxy- and 5-Hydroxy-1,3-dioxane 1

✍ Scribed by Vázquez-Hernández, Maribel; Rosquete-Pina, Giselle A.; Juaristi, Eusebio


Book ID
127182100
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
371 KB
Volume
69
Category
Article
ISSN
0022-3263

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Contrasting conformational behavior of 5
✍ J.Samuel Cruz-Sánchez; Eusebio Juaristi 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 206 KB

The preparation of novel 1,3-dithiane derivatives, cis-and trans-2-tert-butyl-5-methylsulfonyl-1,3-dithiane, was achieved by acid-catalyzed condensation of 2-methylsulfonyl-1,3-propanedithiol with pivalaldehyde. The former dithiol was obtained from allylmethylsulfide via the Knochel-Normant brominat