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Salt Effects in the Stereochemistry of Acetolysis of 2-Octyl p-Toluenesulfonate 1

โœ Scribed by Streitwieser, A.; Walsh, T. D.


Book ID
126951884
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
746 KB
Volume
87
Category
Article
ISSN
0002-7863

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Stereochemistry of acetolysis of 2-octyl
โœ A. Streitwieser Jr.; T.D. Walsh ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 331 KB

SOLVOLYSES of secondary alkyl systems frequently fall in the "borderline" region of solvolytic behavior in which controversy about detailed mechanism still exists. Especially interesting is the reaction of simple secondary alkyl sulfonates in acetic acid in which various criteria suggest a limiting