Eight azo dyes containing the 4,S-diphenylimidazolc group have been synthesized, and their potential for determinations of metals has been studied spcctrophotomctrically. Of these reagents, the pyridylazo and quinolylazo derivatives are suitable as chromogenic reagents, the best being 2-(quinolylazo
Salinogenic or chelate forming dyes as analytical reagents
β Scribed by Steigmann, A.
- Book ID
- 102327210
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1947
- Weight
- 415 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0368-4075
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β¦ Synopsis
TABLE XIX -_ Qipric acetate/acctic acid solutiorrs Test solution Metal Observations I yo CuAc,, I yo HAc Absent Formation of black lustrous sales after 10 hours 1% CuAc,, s: L HAc ,, Formation of black lustrous s a l e s after 30 hours. (See also Table -1-STEIGMA NN-ANAL YTICAL REAGENTS 353 1% CuAc,, IO?(, HAc ,, z%HAc .. .. Copperand !yo HAc . . . . 60140 brass 1% Cu.4cZ, 1yn HAc Copper and > . I ,, 5yo HAc 60/40 brass " ,, roo/, HAc ' ,, zoyoHAc ,, so' :; HAc ,) IooD,b HAC '1% CuAc,, 5% HAc Alloys u-2 A l l No ppt after 60 hrs. No acetylidc formation after prolonged passage of C,H, In all uses a black film of ncctylide formed on both metals within 10 min. except in the
π SIMILAR VOLUMES