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Salicifoline and salicinolide, new diterpene polyesters from Euphorbia salicifolia

✍ Scribed by Judit Hohmann; Ferenc Evanics; György Dombi; Pál Szabó


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
79 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


Two new diterpenes (1 and 2) were isolated from a dichloromethane extract of fresh, whole plants of Euphorbia salicifolia: salicifoline (1) is the first representative of a new type of tricyclic diterpenes involving a novel 5-8-8 fused ring system, and salicinolide ( 2) is a bishomoditerpene lactone based on the jatrophane skeleton. The carbon skeleton of 1 is formally derived from jatrophane via transannular intramolecular C C bond formation between C-12 and C-17.


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