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Salen ligands derived from trans-1,2-dimethyl-1,2-cyclohexanediamine: preparation and application in oxo-chromium salen mediated asymmetric epoxidation of alkenes

✍ Scribed by Nessan J. Kerrigan; Helge Müller-Bunz; Declan G. Gilheany


Book ID
108211429
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
216 KB
Volume
227
Category
Article
ISSN
1381-1169

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The synthesis and use in asymmetric epox
✍ Adrian M. Daly; Declan G. Gilheany 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 273 KB

A complete synthesis of enantiopure trans-cyclopentane-1,2-diamine and trans-cyclobutane-1,2-diamine is described. These diamines have been used as components of novel chiral salen ligands whose chromium and manganese complexes were then evaluated as oxygen transfer agents in the asymmetric epoxidat