Saccharide Sensing Based on Saccharide-Induced Conformational Changes in Fluorescent Boronic Acid Polymers
✍ Scribed by Yasumasa Kanekiyo; Hiroaki Sato; Hiroaki Tao
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 112 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
Summary: A novel fluorometric saccharide detection strategy has been established by utilizing saccharide‐induced conformational changes in copolymers containing boronic acid and fluorescent units. The polymer chain changes its conformation due to an alteration of the charge state induced by binding with saccharides. The conformational changes are conveniently detected by monitoring excimer to monomer intensity ratio in the fluorescence spectra. Thus, the present strategy would be a promising way for the creation of highly selective and sensitive saccharide‐sensing systems.
Saccharide‐induced conformational change in copolymers containing boronic acid units.
magnified imageSaccharide‐induced conformational change in copolymers containing boronic acid units.
📜 SIMILAR VOLUMES
The memory effect of the D-threitol-or L-threitol-imprinted 160lfullerene-bisadduct [(fc)-4 or (fA)-4], which was obtained from the double addition reaction between [601fullerene and D-threitol-or L-threitol-boronic acid 1:2 complex (D-1 or L-I), was discussed. In the competitive complexation with D