S9.16 Determination of linkage positions by FAB-mass spectrometry
✍ Scribed by L. Blok-Tip; J. Hirsch; V. Kováčik; W. Heerma; J. Haverkamp
- Book ID
- 105119186
- Publisher
- Springer US
- Year
- 1993
- Tongue
- English
- Weight
- 124 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1573-4986
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## Abstract Negative‐ion electrospray mass spectrometry was used to determine directly both glycosidic linkage position and anomeric configuration in the complete glucopyranosyl disaccharide series without the need for derivatization or tandem mass analysis. A series of empirical criteria were deve
Application of f.a.b.-m.s. to the products obtained from glycoconjugates upon periodate oxidation followed by borohydridc reduction and methylation gives the positions of binding of the monosaccharide residues on the basis of the sequences of the primary and secondary ions. ## INTRODUClION The in